General Chemistry |

- 1Introduction to Chemistry
  - 1.1Chemistry in the Modern World
  - 1.2The Scientific Method
  - 1.3A Description of Matter
  - 1.4A Brief History of Chemistry
  - 1.5The Atom
  - 1.6Isotopes and Atomic Masses
  - 1.7Introduction to the Periodic Table
  - 1.8Essential Elements for Life
  - 1.9Essential Skills 1
  - 1.10End-of-Chapter Material
- 2Molecules, Ions, and Chemical Formulas
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  - 2.1Chemical Compounds
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  - 2.2Chemical Formulas
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  - 2.3Naming Ionic Compounds
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  - 2.4Naming Covalent Compounds
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  - 2.5Acids and Bases
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  - 2.6Industrially Important Chemicals
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  - 2.7End-of-Chapter Material
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- 3Chemical Reactions
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  - 3.1The Mole and Molar Masses
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  - 3.2Determining Empirical and Molecular Formulas
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  - 3.3Chemical Equations
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  - 3.4Mass Relationships in Chemical Equations
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  - 3.5Classifying Chemical Reactions
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  - 3.6Chemical Reactions in the Atmosphere
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  - 3.7Essential Skills 2
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  - 3.8End-of-Chapter Material
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- 4Reactions in Aqueous Solution
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  - 4.1Aqueous Solutions
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  - 4.2Solution Concentrations
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  - 4.3Stoichiometry of Reactions in Solution
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  - 4.4Ionic Equations
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  - 4.5Precipitation Reactions
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  - 4.6Acid–Base Reactions
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  - 4.7The Chemistry of Acid Rain
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  - 4.8Oxidation–Reduction Reactions in Solution
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  - 4.9Quantitative Analysis Using Titrations
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  - 4.10Essential Skills 3
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  - 4.11End-of-Chapter Material
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- 5Energy Changes in Chemical Reactions
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  - 5.1Energy and Work
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  - 5.2Enthalpy
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  - 5.3Calorimetry
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  - 5.4Thermochemistry and Nutrition
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  - 5.5Energy Sources and the Environment
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  - 5.6Essential Skills 4
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  - 5.7End-of-Chapter Material
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- 6The Structure of Atoms
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  - 6.1Waves and Electromagnetic Radiation
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  - 6.2The Quantization of Energy
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  - 6.3Atomic Spectra and Models of the Atom
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  - 6.4The Relationship between Energy and Mass
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  - 6.5Atomic Orbitals and Their Energies
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  - 6.6Building Up the Periodic Table
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  - 6.7End-of-Chapter Material
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- 7The Periodic Table and Periodic Trends
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  - 7.1The History of the Periodic Table
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  - 7.2Sizes of Atoms and Ions
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  - 7.3Energetics of Ion Formation
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  - 7.4The Chemical Families
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  - 7.5Trace Elements in Biological Systems
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  - 7.6End-of-Chapter Material
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- 8Ionic versus Covalent Bonding
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  - 8.1An Overview of Chemical Bonding
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  - 8.2Ionic Bonding
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  - 8.3Lattice Energies in Ionic Solids
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  - 8.4Lewis Electron Dot Symbols
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  - 8.5Lewis Structures and Covalent Bonding
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  - 8.6Exceptions to the Octet Rule
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  - 8.7Lewis Acids and Bases
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  - 8.8Properties of Covalent Bonds
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  - 8.9Polar Covalent Bonds
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  - 8.10End-of-Chapter Material
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- 9Molecular Geometry and Covalent Bonding Models
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  - 9.1Predicting the Geometry of Molecules and Polyatomic Ions
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  - 9.2Localized Bonding and Hybrid Atomic Orbitals
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  - 9.3Delocalized Bonding and Molecular Orbitals
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  - 9.4Polyatomic Systems with Multiple Bonds
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  - 9.5End-of-Chapter Material
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- 10Gases
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  - 10.1Gaseous Elements and Compounds
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  - 10.2Gas Pressure
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  - 10.3Relationships among Pressure, Temperature, Volume, and Amount
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  - 10.4The Ideal Gas Law
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  - 10.5Mixtures of Gases
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  - 10.6Gas Volumes and Stoichiometry
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  - 10.7The Kinetic Molecular Theory of Gases
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  - 10.8The Behavior of Real Gases
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  - 10.9Essential Skills 5
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  - 10.10End-of-Chapter Material
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- 11Liquids
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  - 11.1The Kinetic Molecular Description of Liquids
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  - 11.2Intermolecular Forces
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  - 11.3Unique Properties of Liquids
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  - 11.4Vapor Pressure
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  - 11.5Changes of State
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  - 11.6Critical Temperature and Pressure
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  - 11.7Phase Diagrams
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  - 11.8Liquid Crystals
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  - 11.9Essential Skills 6
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  - 11.10End-of-Chapter Material
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- 12Solids
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  - 12.1Crystalline and Amorphous Solids
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  - 12.2The Arrangement of Atoms in Crystalline Solids
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  - 12.3Structures of Simple Binary Compounds
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  - 12.4Defects in Crystals
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  - 12.5Correlation between Bonding and the Properties of Solids
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  - 12.6Bonding in Metals and Semiconductors
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  - 12.7Superconductors
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  - 12.8Polymeric Solids
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  - 12.9Contemporary Materials
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  - 12.10End-of-Chapter Material
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- 13Solutions
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  - 13.1Factors Affecting Solution Formation
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  - 13.2Solubility and Molecular Structure
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  - 13.3Units of Concentration
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  - 13.4Effects of Temperature and Pressure on Solubility
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  - 13.5Colligative Properties of Solutions
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  - 13.6Aggregate Particles in Aqueous Solution
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  - 13.7End-of-Chapter Material
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- 14Chemical Kinetics
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  - 14.1Factors That Affect Reaction Rates
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  - 14.2Reaction Rates and Rate Laws
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  - 14.3Methods of Determining Reaction Order
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  - 14.4Using Graphs to Determine Rate Laws, Rate Constants, and Reaction Orders
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  - 14.5Half-Lives and Radioactive Decay Kinetics
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  - 14.6Reaction Rates—A Microscopic View
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  - 14.7The Collision Model of Chemical Kinetics
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  - 14.8Catalysis
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  - 14.9End-of-Chapter Material
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- 15Chemical Equilibrium
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  - 15.1The Concept of Chemical Equilibrium
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  - 15.2The Equilibrium Constant
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  - 15.3Solving Equilibrium Problems
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  - 15.4Nonequilibrium Conditions
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  - 15.5Factors That Affect Equilibrium
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  - 15.6Controlling the Products of Reactions
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  - 15.7Essential Skills
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  - 15.8End-of-Chapter Material
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- 16Aqueous Acid–Base Equilibriums
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  - 16.1The Autoionization of Water
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  - 16.2A Qualitative Description of Acid–Base Equilibriums
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  - 16.3Molecular Structure and Acid–Base Strength
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  - 16.4Quantitative Aspects of Acid–Base Equilibriums
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  - 16.5Acid–Base Titrations
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  - 16.6Buffers
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  - 16.7End-of-Chapter Material
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- 17Solubility and Complexation Equilibriums
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  - 17.1Determining the Solubility of Ionic Compounds
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  - 17.2Factors That Affect Solubility
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  - 17.3The Formation of Complex Ions
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  - 17.4Solubility and pH
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  - 17.5Qualitative Analysis Using Selective Precipitation
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  - 17.6End-of-Chapter Material
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- 18Chemical Thermodynamics
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  - 18.1Thermodynamics and Work
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  - 18.2The First Law of Thermodynamics
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  - 18.3The Second Law of Thermodynamics
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  - 18.4Entropy Changes and the Third Law of Thermodynamics
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  - 18.5Free Energy
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  - 18.6Spontaneity and Equilibrium
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  - 18.7Comparing Thermodynamics and Kinetics
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  - 18.8Thermodynamics and Life
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  - 18.9End-of-Chapter Material
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- 19Electrochemistry
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  - 19.1Describing Electrochemical Cells
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  - 19.2Standard Potentials
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  - 19.3Comparing Strengths of Oxidants and Reductants
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  - 19.4Electrochemical Cells and Thermodynamics
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  - 19.5Commercial Galvanic Cells
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  - 19.6Corrosion
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  - 19.7Electrolysis
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  - 19.8End-of-Chapter Material
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- 20Nuclear Chemistry
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  - 20.1The Components of the Nucleus
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  - 20.2Nuclear Reactions
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  - 20.3The Interaction of Nuclear Radiation with Matter
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  - 20.4Thermodynamic Stability of the Atomic Nucleus
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  - 20.5Applied Nuclear Chemistry
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  - 20.6The Origin of the Elements
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  - 20.7End-of-Chapter Material
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- 21Periodic Trends and the s-Block Elements
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  - 21.1Overview of Periodic Trends
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  - 21.2The Chemistry of Hydrogen
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  - 21.3The Alkali Metals (Group 1)
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  - 21.4The Alkaline Earth Metals (Group 2)
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  - 21.5The s-Block Elements in Biology
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- 22The p-Block Elements
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  - 22.1The Elements of Group 13
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  - 22.2The Elements of Group 14
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  - 22.3The Elements of Group 15 (The Pnicogens)
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  - 22.4The Elements of Group 16 (The Chalcogens)
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  - 22.5The Elements of Group 17 (The Halogens)
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  - 22.6The Elements of Group 18 (The Noble Gases)
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  - 22.7End-of-Chapter Material
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- 23The d-Block Elements
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  - 23.1General Trends among the Transition Metals
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  - 23.2A Brief Survey of Transition-Metal Chemistry
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  - 23.3Metallurgy
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  - 23.4Coordination Compounds
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  - 23.5Crystal Field Theory
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  - 23.6Transition Metals in Biology
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  - 23.7End-of-Chapter Material
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- 24Organic Compounds
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  - 24.1Functional Groups and Classes of Organic Compounds
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  - 24.2Isomers of Organic Compounds
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  - 24.3Reactivity of Organic Molecules
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  - 24.4Common Classes of Organic Reactions
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  - 24.5Common Classes of Organic Compounds
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  - 24.6The Molecules of Life
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  - 24.7End-of-Chapter Material
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- AStandard Thermodynamic Quantities for Chemical Substances at 25°C
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- BSolubility-Product Constants (Ksp) for Compounds at 25°C
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- CDissociation Constants and pKa Values for Acids at 25°C
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- DDissociation Constants and pKb Values for Bases at 25°C
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- EStandard Reduction Potentials at 25°C
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- FProperties of Water
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- GPhysical Constants and Conversion Factors
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- HPeriodic Table of Elements
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- IExperimentally Measured Masses of Selected Isotopes
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- JArt and Photo Credits
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  - J.1Molecular Models
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  - J.2Photo Credits
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